http://10.10.120.238:8080/xmlui/handle/123456789/663| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Nagaraju K. | en_US |
| dc.contributor.author | Gurubrahamam R. | en_US |
| dc.contributor.author | Gurubrahamam R. | en_US |
| dc.contributor.author | Chen K. | en_US |
| dc.date.accessioned | 2023-11-30T08:44:51Z | - |
| dc.date.available | 2023-11-30T08:44:51Z | - |
| dc.date.issued | 2020 | - |
| dc.identifier.issn | 0022-3263 | - |
| dc.identifier.other | EID(2-s2.0-85087372295) | - |
| dc.identifier.uri | https://dx.doi.org/10.1021/acs.joc.0c00431 | - |
| dc.identifier.uri | http://localhost:8080/xmlui/handle/123456789/663 | - |
| dc.description.abstract | To construct multisubstituted seven-membered nitrogenous heterocyclic scaffolds, an efficient method, employing 2-aminoaryl N-monosubstituted hydrazones and 2-oxo-3-butenoates under Brønsted acid catalysis, has been developed. This strategy highlights the umpolung reactivity of 2-aminobenzaldehyde arylhydrazones toward 2-oxo-3-butenoates to afford (E)-diazoaryl-benzo[b]azepine derivatives in excellent yields (89-99%) and with high diastereoselectivities (>19:1 dr). Copyright © 2020 American Chemical Society. | en_US |
| dc.language.iso | en | en_US |
| dc.publisher | American Chemical Society | en_US |
| dc.source | Journal of Organic Chemistry | en_US |
| dc.title | Organocatalytic Diastereoselective Synthesis of Diazoaryl-benzo[b]azepine Derivatives | en_US |
| dc.type | Journal Article | en_US |
| Appears in Collections: | Journal Article | |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.