http://10.10.120.238:8080/xmlui/handle/123456789/591
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kotwal N. | en_US |
dc.contributor.author | Tamanna N. | en_US |
dc.contributor.author | Changotra A. | en_US |
dc.contributor.author | Chauhan P. | en_US |
dc.date.accessioned | 2023-11-30T08:42:13Z | - |
dc.date.available | 2023-11-30T08:42:13Z | - |
dc.date.issued | 2023 | - |
dc.identifier.issn | 1523-7060 | - |
dc.identifier.other | EID(2-s2.0-85174641153) | - |
dc.identifier.uri | https://dx.doi.org/10.1021/acs.orglett.3c02832 | - |
dc.identifier.uri | http://localhost:8080/xmlui/handle/123456789/591 | - |
dc.description.abstract | We disclose herein a highly diastereo- and enantioselective divergent synthesis of seven-membered biaryl-bridged carbo- and oxacyclic frameworks by utilizing the catalytic ability of bifunctional hydrogen-bonding squaramide organocatalysts. Starting with the same biaryl substrate bearing two distinct acceptor sites and by choosing soft or hard nucleophiles, we readily accessed the dibenzocycloheptanes or 5,7-dihydrodibenzo[c,e]oxepines bearing multiple elements of chirality via a domino 1,4/1,2-addition or 1,2/oxa-Michael addition sequence, respectively. © 2023 American Chemical Society | en_US |
dc.language.iso | en | en_US |
dc.publisher | American Chemical Society | en_US |
dc.source | Organic Letters | en_US |
dc.title | Organocatalytic Asymmetric Synthesis of Carbo- and Oxacyclic Seven-Membered Bridged Biaryls via Nucleophile-Dependent Switchable Domino Processes | en_US |
dc.type | Journal Article | en_US |
Appears in Collections: | Journal Article |
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